Focus on Cellulose ethers

What are the reasons that affect the water retention of hydroxypropyl methylcellulose?

The higher the viscosity of hydroxypropyl methylcellulose, the better the water retention performance. Viscosity is an important parameter of HPMC performance. At present, different HPMC manufacturers use different methods and instruments to measure the viscosity of HPMC. The main methods are HaakeRotovisko, Hoppler, Ubbelohde and Brookfield.

For the same product, the viscosity results measured by different methods are very different, and some even have doubled differences. Therefore, when comparing viscosity, it must be carried out between the same test methods, including temperature, rotor, etc.

Regarding particle size, the finer the particle, the better the water retention. After the large particles of cellulose ether come into contact with water, the surface immediately dissolves and forms a gel to wrap the material to prevent water molecules from continuing to infiltrate. Sometimes it cannot be uniformly dispersed and dissolved even after long-term stirring, forming a cloudy flocculent solution or agglomeration . It greatly affects the water retention of cellulose ether, and solubility is one of the factors for choosing cellulose ether.

Fineness is also an important performance index of methyl cellulose ether. The MC used for dry powder mortar is required to be powder, with low water content, and the fineness also requires 20%-60% of the particle size to be less than 63um. The fineness affects the solubility of hydroxypropyl methylcellulose ether. Coarse MC is usually granular, and it is easy to dissolve in water without agglomeration, but the dissolution rate is very slow, so it is not suitable for use in dry powder mortar.

In dry powder mortar, MC is dispersed among cementing materials such as aggregate, fine filler and cement, and only fine enough powder can avoid methyl cellulose ether agglomeration when mixing with water. When MC is added with water to dissolve the agglomerates, it is very difficult to disperse and dissolve. Coarse fineness of MC is not only wasteful, but also reduces the local strength of the mortar. When such a dry powder mortar is applied in a large area, the curing speed of the local dry powder mortar will be significantly reduced, and cracks will appear due to different curing times. For the sprayed mortar with mechanical construction, the requirement for fineness is higher due to the shorter mixing time.

Generally speaking, the higher the viscosity, the better the water retention effect. However, the higher the viscosity and the higher the molecular weight of MC, the corresponding decrease in its solubility will have a negative impact on the strength and construction performance of the mortar. The higher the viscosity, the more obvious the thickening effect on the mortar, but it is not directly proportional. The higher the viscosity, the more viscous the wet mortar will be, that is, during construction, it is manifested as sticking to the scraper and high adhesion to the substrate. But it is not helpful to increase the structural strength of the wet mortar itself. During construction, the anti-sag performance is not obvious. On the contrary, some medium and low viscosity but modified methyl cellulose ethers have excellent performance in improving the structural strength of wet mortar.

The greater the amount of cellulose ether added to the mortar, the better the water retention performance, and the higher the viscosity, the better the water retention performance.

The fineness of HPMC also has a certain impact on its water retention. Generally speaking, for methyl cellulose ethers with the same viscosity but different fineness, under the same addition amount, the finer the finer the better the water retention effect.

The water retention of HPMC is also related to the temperature used, and the water retention of methyl cellulose ether decreases with the increase of temperature. However, in actual material applications, dry powder mortar is often applied to hot substrates at high temperatures (higher than 40 degrees) in many environments, such as exterior wall putty plastering under the sun in summer, which often accelerates Curing of cement and hardening of dry powder mortar.

The decline of water retention rate leads to the obvious feeling that both workability and crack resistance are affected, and it is particularly critical to reduce the influence of temperature factors under this condition. Although methyl hydroxyethyl cellulose ether additives are currently considered to be at the forefront of technological development, their dependence on temperature will still lead to weakening of the performance of dry powder mortar.

Increase the amount of methyl hydroxyethyl cellulose, workability and crack resistance still can not meet the needs of use. Through some special treatment on MC, such as increasing the degree of etherification, etc., the water retention effect can be maintained at a higher temperature, so that it can provide better performance under harsh conditions.

Post time: Apr-10-2023
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